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Selectivity of the bulky proton-containing reagent N-methyl-N,O-bis(trimethylsilyl)hydroxylamine in the formation of nitrones.

Journal of Organometallic Chemistry (1990) 399(3)
DOI: 10.1016/0022-328X(90)85501-O
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Abstract

Silicon reagent Me3SiN(ME)OSiMe3 contains bulky protons (i.e. Me3Si+). This reagent was found to possess regio- and chemoselectivities in the formation of nitrones from carbonyl compounds. © 1990.

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Hwu, J. R., Khoudhary, kevin P., & Tsay, S. C. (1990). Selectivity of the bulky proton-containing reagent N-methyl-N,O-bis(trimethylsilyl)hydroxylamine in the formation of nitrones. Journal of Organometallic Chemistry, 399(3). https://doi.org/10.1016/0022-328X(90)85501-O

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