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Aromatic boranes with planar-tetracoordinate boron atoms and very short B-B distances

Angewandte Chemie - International Edition (2002) 41(9) 1526-1529
DOI: 10.1002/1521-3773(20020503)41:9<1526::AID-ANIE1526>3.0.CO;2-Y
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Abstract

The diamond-shaped tetraborane(6) 1 and its pyridine adduct 2 are the first aromatic compounds in two πelectrons display cyclic F delocalization over four and three boron centers, respectively (see scheme). The two compounds contain the shortest B-B distances ever observed. R = SiMe3, Pyr = 4-tertbutylpyridine.

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Präsang, C., Hofmann, M., Geiseler, G., Massa, W., & Berndt, A. (2002). Aromatic boranes with planar-tetracoordinate boron atoms and very short B-B distances. Angewandte Chemie - International Edition, 41(9), 1526–1529. https://doi.org/10.1002/1521-3773(20020503)41:9<1526::AID-ANIE1526>3.0.CO;2-Y

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