Spin-flip limited exciton dephasing in CdSe/ZnS colloidal quantum dots

Abstract

The dephasing time of the lowest bright exciton in CdSe/ZnS wurtzite quantum dots is measured from 5 to 170K and compared with density dynamics within the exciton fine structure using a sensitive three-beam four-wave-mixing technique unaffected by spectral diffusion. Pure dephasing via acoustic phonons dominates the initial dynamics, followed by an exponential zero-phonon line dephasing of 109ps at 5K, much faster than the 10 ns exciton radiative lifetime. The zero-phonon line dephasing is explained by phonon-assisted spin flip from the lowest bright state to dark-exciton states. This is confirmed by the temperature dependence of the exciton lifetime and by direct measurements of the bright-darkexciton relaxation. Our results give an unambiguous evidence of the physical origin of the exciton dephasing in these nanocrystals. © 2012 American Physical Society.