Abstract
A new type of O-alkylation of 2-hydroxy-1,4-naphthoquinone with alkoxymethyl chlorides is described. The reaction course can be controlled by the choice of base and yields Oalkylated or O-alkoxymethylated products in high yield with high selectivity.
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Ogata, T., Yoshida, T., Tanaka, M., Fukuhara, C., Shimizu, M., Ishii, J., … Kimachi, T. (2015). Unusual O-alkylation of 2-hydroxy-1,4-naphthoquinone utilizing alkoxymethyl chlorides. Chemical and Pharmaceutical Bulletin, 63(7), 485–488. https://doi.org/10.1248/cpb.c15-00220
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