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Recyclable polymeric π-acid catalyst effective on Mannich-type reaction in water

Chemical and Pharmaceutical Bulletin (2006) 54(4) 591-593
DOI: 10.1248/cpb.54.591
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Abstract

Polymer-supported dicyanoketene acetal (poly-DCKA-1), synthesized by copolymerization of a DCKA bearing a 4-vinylbenzyl group with ethyleneglycol dimethacrylate, was found to be an excellent recyclable catalyst for the three-component Mannich-type reaction of aldehydes, aromatic amines, and TMS enolate of ethyl isobutyrate in water as the sole solvent. © 2006 Pharmaceutical Society of Japan.

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Masaki, Y., Yamazaki, K., Kawai, H., Yamada, T., Itoh, A., Arai, Y., & Furukawa, H. (2006). Recyclable polymeric π-acid catalyst effective on Mannich-type reaction in water. Chemical and Pharmaceutical Bulletin, 54(4), 591–593. https://doi.org/10.1248/cpb.54.591

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