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Bioinspired dismutation of chlorite to dioxygen and chloride catalyzed by a water-soluble iron porphyrin

Angewandte Chemie - International Edition (2008) 47(40) 7697-7700
DOI: 10.1002/anie.200801521
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Abstract

Cleaning up chlorite: A water-soluble iron porphyrin catalyzes the dismutation of chlorite to dioxygen and chloride. Labeling experiments demonstrate a novel mechanism for O=O bond formation. These mechanistic insights should aid in the design of catalysts for remediation of oxychlorine contaminants. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

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Zdilla, M. J., Lee, A. Q., & Abu-Omar, M. M. (2008). Bioinspired dismutation of chlorite to dioxygen and chloride catalyzed by a water-soluble iron porphyrin. Angewandte Chemie - International Edition, 47(40), 7697–7700. https://doi.org/10.1002/anie.200801521

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