Size reduction-induced properties modifications of antiferromagnetic dielectric nanocrystalline Ba2NiMO6(M = W, Te) double perovskites

Abstract

The main objective of this work was to synthesize phase pure double perovskites Ba2NiTeO6 (BNTO) and Ba2NiWO6 (BNWO) in nanocrystalline form and to reveal the impact of nanocrystallinity on their magnetic and dielectric properties. The studied double perovskites were synthesized in nanocrystalline form by employing a citrate sol-gel route. A detailed investigation of their structure and properties using X-ray powder diffraction, scanning electron microscopy, Raman spectroscopy technique, energy-dispersive X-ray spectroscopy, SQUID magnetometry and electrical measurements is carefully described. Rietveld refinement of X-ray powder diffraction patterns revealed phase purity of both compounds: BNTO is trigonal (R-3m) while BNWO is cubic (Fm-3m). Raman spectroscopy studies reveal optical phonons that correspond to vibrations of Te6+/W6+O6 octahedra, while scanning electron microscopy images show irregular plate-like nanocrystals. Magnetic property measurements speak in favor of antiferromagnetic order but, in both compounds, size reduction affected their properties. BNTO has NCrossed D sign