Nanocatalysts based on dendrimers

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Abstract

Nanostructured regular materials based on dendrimers bound by covalent or coordination bonds between surface functional groups were synthesized. Bimetallic Cu(II) and Pd(II) metal complexes with nitrile-based dendrimers demonstrated high activity in Wacker oxidation of terminal alkenes along with good selectivity for methylketone formation. New heterogeneous catalysts based on Pd nanoparticles and cross-linked polypropylene imine (PPI) and polyamidoamine (PAMAM) dendrimers were prepared and examined for selective hydrogenation of unsaturated compounds. © 2009 IUPAC.

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Karakhanov, E. A., Maximov, A. L., Skorkin, V. A., Zolotukhina, A. V., Smerdov, A. S., & Tereshchenko, A. Y. (2009). Nanocatalysts based on dendrimers. In Pure and Applied Chemistry (Vol. 81, pp. 2013–2023). https://doi.org/10.1351/PAC-CON-08-10-15

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