Back Cover: Intramolecular Frustrated Lewis Pair with the Smallest Boryl Site: Reversible H 2 Addition and Kinetic Analysis (Angew. Chem. Int. Ed. 6/2015)

Konstantin Chernichenko; Bianka Kótai; Imre Pápai; Vladimir Zhivonitko; Martin Nieger; Markku Leskelä; Timo Repo

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Back Cover: Intramolecular Frustrated Lewis Pair with the Smallest Boryl Site: Reversible H 2 Addition and Kinetic Analysis (Angew. Chem. Int. Ed. 6/2015)

Chernichenko K
Kótai B
Pápai I
et al.

Angewandte Chemie International Edition (2015) 54(6) 1976-1976

DOI: 10.1002/anie.201412312

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Abstract

© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. An ansa-aminoborane, an intramolecular frustrated Lewis pair with the smallest Lewis acidic boryl site (BH2), predominantly exists in quenched dimeric form in solution. A monomeric species accountable for hydrogen activation is also present in equilibrium. In their Communication (DOI: 10.1002/anie.201410141), I. Pápai, T. Repo et al. describe the reactivity of this frustrated Lewis pair towards H2 and the corresponding reaction mechanism.

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Chernichenko, K., Kótai, B., Pápai, I., Zhivonitko, V., Nieger, M., Leskelä, M., & Repo, T. (2015). Back Cover: Intramolecular Frustrated Lewis Pair with the Smallest Boryl Site: Reversible H 2 Addition and Kinetic Analysis (Angew. Chem. Int. Ed. 6/2015). Angewandte Chemie International Edition, 54(6), 1976–1976. https://doi.org/10.1002/anie.201412312

Back Cover: Intramolecular Frustrated Lewis Pair with the Smallest Boryl Site: Reversible H 2 Addition and Kinetic Analysis (Angew. Chem. Int. Ed. 6/2015)

Abstract

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