New NLO active cyclopalladated chromophores in main-chain polymers

Abstract

Four new OH-functionalized orthopalladated complexes bearing an electron-donor and an acceptor group in a trans-like arrangement with respect to the metal have been prepared and characterized. The ligands are Schiff bases, bound as C,N- or N,O-chelating moieties. Four new polyesters were obtained by polycondensation from the monomeric complexes and pentyloxyterephthaloyl chloride. Two "model" complexes, each one related to one monomer, were also synthetized, in order to obtain further and more detailed characterization data, and in particular to perform measurements of μβ. © 2003 Elsevier B.V. All rights reserved.