Thermodynamic, chemical, and electrochemical studies of Aloe ferox Mill extract as a naturally developing copper corrosion inhibitor in HCl solution

Abstract

Copper can be susceptible to corrosion in acidic cleaning solutions for desalination system, especially if the solution is highly concentrated or if the cleaning process involves extended exposure to the acid. In the current work, Aloe ferox Mill (AFM extract) can be used as a natural origin corrosion inhibitor for copper in 1.0 M HCl solution. The corrosion mitigation qualities of AFM extract were assessed by means of electrochemical, gravimetric, and surface examinations. AFM extract is a mixed-type inhibitor, based on polarization research findings. The inhibitory effectiveness of AFM extract rises with concentration, reaching its maximum level (93.3%) at 250 mg L–1. The inclusion of AFM extract raises the activation energy for the corrosion reaction from 7.15 kJ mol–1 (blank solution) to 28.6 kJ mol–1 (at 250 mg L–1 AFM extract).