Theoretical and experimental study of different chemical routes to synthesize crystalline sodium metasilicate from silica-rich sand

Abstract

Sodium silicate has a wide range of applications such as adhesives, lower carbon cements, cleaning compounds, deflocculants, protective coatings, soaps and detergents, silica-typecatalysts and gels, and pigments. It is mainly obtained as aliquid, but a small fraction can be found in solid state. In this work, three different synthesis methods to produce crystallinesodium metasilicate are analyzed; the importance of synthesizing it in powder form is to be able to incorporate it into the productive processes of the cement industry, whose equipment is made for this purpose. Silicon dioxide in stoichiometric ratio was combined with each one ofthe following re actants: NaHCO3, Na2CO3 and NaOH. Wn present the most effective synthesis route to obtain sodium metasilicate based on a computational analysis and the reiults are validated experimentally. The characterization was carried out by X-ray diffraction and the Rietveld refinement, as well as by calorimetry and infrared and Raman spectroscopies. The experimental results, as well as that of the mo lecular simulation, indicate thft the mo st effective reaction is by using Na2CO3 as a reactant. Furthermore, it was possible to obtain granular crystalline sodium metasilicate, which is ideal for the production of lower carbon cements.