A novel two dimensional honeycomb-like bimetallic iron(III)-nickel(II) cyanide-bridged magnetic material [Ni(cyclam)]3[Fe(CN)6]2·nH2O (cyclam = 1,4,8,11-tetraazacyclodecane)

Enrique Colacio; José M. Domínguez-Vera; Mustapha Ghazi; Raikko Kivekäs; Francesc Lloret; José M. Moreno; Helen Stoeckli-Evans

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A novel two dimensional honeycomb-like bimetallic iron(III)-nickel(II) cyanide-bridged magnetic material [Ni(cyclam)]3[Fe(CN)6]2·nH2O (cyclam = 1,4,8,11-tetraazacyclodecane)

Chemical Communications (1999) (11) 987-988

DOI: 10.1039/a902041a

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Abstract

The 2D honeycomb-like layered iron(III)-nickel(II) cyanide-bridged complex [Ni(cyclam)]3[Fe(CN)6]2·nH2O exhibits ferromagnetic intralayer and antiferromagnetic interlayer interactions; above 3 K the magnetic properties are typical of a metamagnet with H(c) = 5000 G, whereas below 3 K a canted structure is formed, leading to a long range ferromagnetic ordering.

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Colacio, E., Domínguez-Vera, J. M., Ghazi, M., Kivekäs, R., Lloret, F., Moreno, J. M., & Stoeckli-Evans, H. (1999). A novel two dimensional honeycomb-like bimetallic iron(III)-nickel(II) cyanide-bridged magnetic material [Ni(cyclam)]3[Fe(CN)6]2·nH2O (cyclam = 1,4,8,11-tetraazacyclodecane). Chemical Communications, (11), 987–988. https://doi.org/10.1039/a902041a

A novel two dimensional honeycomb-like bimetallic iron(III)-nickel(II) cyanide-bridged magnetic material [Ni(cyclam)]3[Fe(CN)6]2·nH2O (cyclam = 1,4,8,11-tetraazacyclodecane)

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