9-azanoradamantane N-Oxyl (Nor-AZADO): A highly active organocatalyst for alcohol oxidation

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Abstract

A highly active organocatalyst for alcohol oxidation has been developed. 9-Azanoradamantane N-oxyl (Nor-AZADO 4), constituting an unhindered, stable nitroxyl radical, exhibits superior catalytic activity to 2,2,6,6- tetramethylpiperidine-1-oxyl (TEMPO) and AZADOs in the oxidation of alcohols to their corresponding carbonyl compounds. © 2011 Pharmaceutical Society of Japan.

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Hayashi, M., Sasano, Y., Nagasawa, S., Shibuya, M., & Iwabuchi, Y. (2011). 9-azanoradamantane N-Oxyl (Nor-AZADO): A highly active organocatalyst for alcohol oxidation. Chemical and Pharmaceutical Bulletin, 59(12), 1570–1573. https://doi.org/10.1248/cpb.59.1570

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