Measurement of multicomponent solubility parameters for graphene facilitates solvent discovery

Abstract

We have measured the dispersibility of graphene in 40 solvents, with 28 of them previously unreported. We have shown. that good solvents for graphene are characterized by a Hildebrand solubility parameter of δT ∼ 23 MPal/2 and Hansen solubility parameters of δD ∼18 MPa1/2, δP ∼ 9.3 MPa1/2, and δH ∼7.7 MPa1/2. The dispersibility is smaller for solvents with Hansen parameters further from these values. We have used transmission electron microscopy (TEM) analysis to show that the graphene is well exfoliated in all cases. Even in relatively poor solvents, > 63% of observed, flakes have < 5 layers. © 2009 American Chemical Society.