Abstract
Low-valent uranium(iii) primary phosphido complexes supported by hydrotris(3,5-dimethylpyrazolyl)borate (Tp*) were synthesized with phosphines of varying steric and electronic profiles. Compounds were characterized by multinuclear NMR spectroscopy (1H, 11B, 31P NMR), infrared spectroscopy, electronic absorption spectroscopy, X-ray crystallography, and quantum chemical calculations.
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CITATION STYLE
APA
Perales, D., Bhowmick, R., Zeller, M., Miro, P., Vlaisavljevich, B., & Bart, S. C. (2022). Isolation of uranium(iii) primary phosphido complexes. Chemical Communications, 58(69), 9630–9633. https://doi.org/10.1039/d2cc02207a
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