A simple microextraction method for toxic industrial dyes using a fatty-acid solvent mixture

Abstract

A mixture of dodecanoic and hexanoic fatty acids was used to perform a simple and efficient microextraction method for industrial dyes such as methylene blue (MB), methyl violet (MV), and malachite green (MG) in aqueous solution. The fatty-acid microextractants were simply mixed and heated until the mixture became homogeneous before adding it to the dye solutions. The fatty-acid solvent and its components were characterized with Fourier transform infrared spectroscopy (FTIR) and proton nuclear magnetic resonance (1H NMR) measurements, while the dye concentrations were measured using UV-Vis spectroscopy. The performance of the extracting mixture was observed to vary across different dye contaminants, dosages of the extractant, concentrations of the dyes, and contact times. High extraction efficiencies of up to ~99% were obtained for MG as well as MV, and ~73% efficiency was achieved for MB. The study shows how a mixture of fatty acids can be used as a simple, efficient, green, and sustainable low-volume method for the removal of toxic industrial dyes in aqueous solutions.