Electrochemical reduction of COto organic acids by a Pd-MWNTs gas-diffusion electrode in aqueous medium

Abstract

Pd-multiwalled carbon nanotubes (Pd-MWNTs) catalysts for the conversion of COto organic acids were prepared by the ethylene glycol reduction and fully characterized by Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), transmission electron microscope (TEM), X-ray photoelectron spectroscopy (XPS), and cyclic voltammetry (CV) technologies. The amorphous Pd particles with an average size of 5.7 nm were highly dispersed on the surface of carbon nanotubes. Functional groups of the MWNTs played a key role in the palladium deposition. The results indicated that Pd-MWNTs could transform COinto organic acid with high catalytic activity and COcould take part in the reduction reaction directly. Additionally, the electrochemical reduction of COwas investigated by a diaphragm electrolysis device, using a Pd-MWNTs gas-diffusion electrode as a cathode and a Ti/RuOnet as an anode. The main products in present system were formic acid and acetic acid identified by ion chromatograph. The selectivity of the products could be achieved by reaction conditions changing. The optimum faraday efficiencies of formic and acetic acids formed on the Pd-MWNTs gas-diffusion electrode at 4 V electrode voltages under 1 atm COwere 34.5% and 52.3%, respectively. © 2013 Guang Lu et al.