Platinum Nanoparticles on Sintered Metal Fibers Are Efficient Structured Catalysts in Partial Methane Oxidation into Synthesis Gas

Abstract

Efficient structured catalysts of partial methane oxidation into synthesis gas were obtained by electrochemical modification of the surface of sintered FeCrAl alloy fibers in an ionic liquid BMIM-NTf2 with further introduction of platinum nanoparticles. It was shown that etching and electrochemical modification of sintered FeCrAl alloy fibers result in a decrease of the surface aluminum content. With an increase of the reaction temperature to 900 °C, the methane conversion reaches 90% and the selectivity to CO increases significantly to achieve 98%. The catalysts with a Pt loading of 1 × 10-4 wt % demonstrate high activity and selectivity as well as TOF in synthesis gas production by the CH4 + O2 reaction at 850-900 °C. To trace the composition and structure evolution of the catalysts, XRD and SEM methods were used.