A new Keggin-like niobium-phosphate cluster that reacts reversibly with hydrogen peroxide

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Abstract

Polyoxoniobate clusters that are stable in acidic solutions are rare and particularly useful in industrial processes. Here we report a new pentaphosphate niobate polyoxometalate cluster (TMA)9H3Nb9P5O41·28H2O (Nb9P5) that is stable over a wide pH range and that can be converted reversibly into the peroxo form.

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Son, J. H., & Casey, W. H. (2015). A new Keggin-like niobium-phosphate cluster that reacts reversibly with hydrogen peroxide. Chemical Communications, 51(64), 12744–12747. https://doi.org/10.1039/c5cc03782d

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