Abstract
(+)- or (-)-plnoreslnol: that Is the question. Which of the two enantiomeric lignans is formed during laccasecatalyzed phenol coupling of (E)-coniferyl alcohol (1) depends on the dirigent protein. In the presence of the first enantiocomplementary dirigent protein AtDIR6, (-)-2 is formed (78 % ee). Preferential formation of (+)-2 is observed in the presence of the dirigent protein FiDIR1, whereas only racemic 2 is formed in the absence of dirigent proteins © 2010 Wiley-VCHVerlag GmbH & Co. KCaA, Weinheim.
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Pickel, B., Constantin, M. A., Pfannstiel, J., Conrad, J., Beifuss, U., & Schaller, A. (2010). An enantiocomplementary dirigent protein for the enantioselective lacease-catalyzed oxidative coupling of phenols. Angewandte Chemie - International Edition, 49(1), 202–204. https://doi.org/10.1002/anie.200904622
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