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The Baeyer-Villiger rearrangement with metal triflates: new developments toward mechanism

RSC Advances (2020) 10(36) 21382-21386
DOI: 10.1039/d0ra03335a
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Abstract

Based on MS analysis, the mechanism of the Baeyer-Villiger oxidation of cyclic ketones with hydrogen peroxide using metal triflates (Ga(OTf)3and Er(OTf)3) as catalysts was proposed. In the case of cyclohexanone as a substrate, dimeric, trimeric and tetrameric peroxide structures were detected.

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Latos, P., Siewniak, A., Sitko, M., & Chrobok, A. (2020). The Baeyer-Villiger rearrangement with metal triflates: new developments toward mechanism. RSC Advances, 10(36), 21382–21386. https://doi.org/10.1039/d0ra03335a

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