Mechanical and alkaline hydrothermal treated corn residue conversion in to bioenergy and biofertilizer: A resource recovery concept

Abstract

In this research fall time harvested corn residue (CR) was first mechanically pretreated to produce 5 mm chopped and <500 µm ground particles, which underwent an anaerobic digestion (AD) process to produce biomethane and biofertilizer. Another sample of CR was pretreated by an alkaline hydrothermal (HT) process using 1%, 2% and 3% NaOH to produce solid biocarbon and the resulting alkaline hydrothermal process water (AHTPW), a co-product of biocarbon, underwent fast digestion under AD conditions to produce biomethane and biofertilizer. A predetermined HT process of 240◦C for 30 min was considered and the effect of alkali content on the HT process for biocarbon and biomethane product a rate of 8.21 MJ kg−1 and 9.23 MJ kg−1 of raw CR, respectively. Among the three selected alkaline HT processes, the 1% NaOH HT process produced the highest hybrid bioenergy of 11.39 MJ kg−1 of raw CR with an overall energy recovery of 62.82% of raw CR. The AHTPW of 2% and 3% NaOH HT-treated CR did not produce considerable amount of biomethane and their biocarbons contained 3.44 MJ kg−1 and 3.27 MJ kg−1 of raw CR of bioenergy, respectively. The biomethane produced from 5 mm chopped CR, <500 µm ground CR and 1% alkaline AHTPW for 30 days retention time were of 275.38 L kg−1 volatile solid (VS), 309.59 L kg−1 VS and 278.70 L kg−1 VS, respectively, compared to non-treated CR of 144-187 L kg−1 VS. Nutrient enriched AD digestate is useable as liquid fertilizer. Biocarbon, biomethane and biofertilizer produced from the 1% alkaline HT process at 240◦C for 30 min can reduce the greenhouse gas (GHG) emissions of Ontario.