Germaborenes: Borylene Transfer Agents for the Synthesis of Iminoboranes

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Abstract

Halide and phenyl substituted germaborenes were shown to react with azides at room temperature and transfer a borylene moiety to give iminoboranes. This iminoborane synthesis based on a borylene transfer route was investigated computationally in the case of the phenyl substituted germaborene.

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Raiser, D., Schubert, H., Bettinger, H. F., & Wesemann, L. (2021). Germaborenes: Borylene Transfer Agents for the Synthesis of Iminoboranes. Chemistry - A European Journal, 27(6), 1981–1983. https://doi.org/10.1002/chem.202004579

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