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Dimerization of ethynylaniline to a quinoline derivative using a ruthenium/gold heterobimetallic catalyst

Arkivoc (2010) 2010(8) 160-166
DOI: 10.3998/ark.5550190.0011.813
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Abstract

Dimerization of 2-ethynylaniline in the presence of the Ru/Au complexes CpRu(PPh3)Cl(μ-dppm)AuCl or CpRu(PPh3)I(μ-dppm)AuI results in formation of a quinoline derivative. Monometallic model compounds for the Ru and Au centers did not catalyze the dimerization reaction. This transformation proceeds in higher yield in the absence of solvent.

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Shelton, P. A., Hilliard, C. R., Swindling, M., & McElwee-White, L. (2010). Dimerization of ethynylaniline to a quinoline derivative using a ruthenium/gold heterobimetallic catalyst. Arkivoc, 2010(8), 160–166. https://doi.org/10.3998/ark.5550190.0011.813

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