Variation of Kβ/Kα x-ray intensity ratios in 3d elements

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Abstract

The Kβ/Kα x-ray intensity ratios for compounds of 3d elements were calculated with the discrete-variational Xα (DV-Xα) molecular orbital method. It was found that the calculated results for V and Cr compounds are strongly correlated with the effective number of 3d electrons. The Kβ/Kα ratio is expressed as a linear function of the number of 3d electrons, but the slope of the straight line is different for different crystal symmetries. The Kβ/Kα ratio for Td symmetry is generally larger than that for Oh. Copyright © 2000 John Wiley & Sons, Ltd.

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Mukoyama, T., Taniguchi, K., & Adachi, H. (2000). Variation of Kβ/Kα x-ray intensity ratios in 3d elements. X-Ray Spectrometry, 29(6), 426–429. https://doi.org/10.1002/1097-4539(200011/12)29:6<426::AID-XRS447>3.0.CO;2-O

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