Hydrolytic depolymerisation of polyesters over heterogeneous ZnO catalyst

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Abstract

The hydrolytic depolymerisation of polylactic acid (PLA) and polyethylene terephthalate (PET) was accomplished in neat water using heterogenous ZnO catalysts. Up to 100% and 98% selectivity to the complete hydrolysis products was achieved at full PLA and PET conversion at 130 °C and 180 °C, respectively. The catalytic species could be partially (for PLA) recovered and reused, though with a gradual activity drop.

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Liguori, F., Moreno-Marrodán, C., Oberhauser, W., Passaglia, E., & Barbaro, P. (2023). Hydrolytic depolymerisation of polyesters over heterogeneous ZnO catalyst. RSC Sustainability, 1(6), 1394–1403. https://doi.org/10.1039/d3su00089c

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