Quantitative XRD analysis of the structural changes of ba-exchanged montmorillonite: Effect of an in situ hydrous perturbation

Abstract

The structural changes along the c axis, of the Ba-exchanged montmorillonite (Swy-2-Ba), under variable relative humidity (% RH), is investigated. In this regard, the arrangement, amount and position of both exchangeable cation and the water molecules in the interlamellar space (IS), are evaluated. This aim is achieved using the X-ray diffraction (XRD) profile modeling approach that consists of comparing experimental and theoretical patterns calculated from structural models. The contributions of the hydration states and the interlayer water amounts, as a function of the % RH, are registered by quantitative XRD investigation. The validated structural models are heterogeneous, suggesting various proportions of layer types at different RH ranges, which means the coexistence of different mixed layer structure MLS packages, exhibiting different proportions of layers with contrasting hydration states. This result is attributed to the orientation of the applied hydration sequence. Indeed, the interlayer water molecule amounts, which led to the appearance of a logic hydration hysteresis, are strongly affected by hydrous perturbation.