Preparation of polyvinyl alcohol/xylan blending films with 1,2,3,4-butane tetracarboxylic acid as a new plasticizer

Abstract

Miscible, biodegradable polyvinyl alcohol (PVA)/xylan blending films were firstly prepared in the range of the PVA/xylan weight ratio from 1: 2 to 3: 1 by casting method using 1,2,3,4-butane tetracarboxylic acid (BTCA) as a new plasticizer. The properties of blending films as functions of PVA/xylan weight ratio and BTCA amount were discussed. XRD and FT-IR were applied to characterize the blending films. Experimental results indicated that tensile strength (TS) and elongation at break (EAB) of blending films decreased along with the decrease of the PVA/xylan weight ratio. Both of TS and EAB firstly increased and then decreased as the amount of BTCA was increased. More importantly, blending films were biodegraded almost by 41% with an addition of 10% BTCA in blending films within 30 days in soil. For all hydroxyl functionalized polymers (xylan and PVA), their molecular interactions and miscibility with BTCA endowed blending films with the biocompatibility and biodegradability. Therefore, these blending films are environmentally friendly materials which could be applied as biodegradable plastics for food packaging and agricultural applications. © 2014 Cun-dian Gao et al.