Hexakis(thiourea-κS)nickel(II) nitrate: A redetermination

Abstract

A preliminary X-ray study of the title mol-ecular salt, [Ni(CH 4N2S)6](NO3)2, has been reported twice previously, by Maďar [Acta Cryst. (1961), 14, 894] and Rodriguez, Cubero, Vega, Morente & Vazquez [Acta Cryst. (1961), 14, 1101], using film methods. We confirm the previous studies, but to modern standards of precision and with all H atoms located. The central Ni atom (site symmetry 1̄) of the dication is octahedrally coordinated by six S-bound thio-urea molecules. The crystal structure is stabilized by intra- and intermolecular N - H⋯S and N - H⋯O hydrogen bonds.