Journal Article

Acid-base driven ligand exchange with palladium(II) "Click" complexes

Asian Journal of Organic Chemistry (2015) 4(3) 208-211
DOI: 10.1002/ajoc.201402197
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Abstract

Two simple palladium(II) pyridine-2,6-dicarboxamide complexes coordinated to CuAAC derived "click" 1,2,3-triazole ligands are described. Addition of a more basic 4-dimethylaminopyridine (DMAP) ligand to these palladium(II) "click" complexes leads to complete displacement of the 1,2,3-triazole ligands by DMAP. The process can be completely reversed by treatment with acid.

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Noor, A., Maloney, D. L., Lewis, J. E. M., Lo, W. K. C., & Crowley, J. D. (2015). Acid-base driven ligand exchange with palladium(II) “Click” complexes. Asian Journal of Organic Chemistry, 4(3), 208–211. https://doi.org/10.1002/ajoc.201402197

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