Upgrading biogenic furans: Blended C10-C12 platform chemicals via lyase-catalyzed carboligations and formation of novel C12 - Choline chloride-based deep-eutectic-solvents

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Abstract

Benzaldehyde lyase (BAL) results in an efficient biocatalyst for the umpolung carboligation of furfural, HMF, and mixtures of them, leading to blended C10-C12 platform chemicals. Subsequently, the mixing and gentle heating (<100°C) of the formed hydroxy-ketone with choline chloride leads to the formation of a novel biomass-derived deep-eutectic-solvent.

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Donnelly, J., Müller, C. R., Wiermans, L., Chuck, C. J., & Domínguez De María, P. (2015). Upgrading biogenic furans: Blended C10-C12 platform chemicals via lyase-catalyzed carboligations and formation of novel C12 - Choline chloride-based deep-eutectic-solvents. Green Chemistry, 17(5), 2714–2718. https://doi.org/10.1039/c5gc00342c

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