Preparation of new modified silica gel terminated with phenylphosphonic acid-amide moieties for adsorption of uranium(VI) from aqueous solutions

Abstract

PAMAM dendrimers modified silica gel terminated phenylphosphonic acid-amide moieties (Si-6G PAMAM-PPAAM) was prepared for uranium(VI) adsorption from aqueous solutions by batch and fixed-bed column methods. The experimental results showed that the maximum capacity was 434.78 mg g−1. Equilibrium isotherm data obeyed Langmuir isotherm model. Kinetic adsorption followed pseudo-second order model and thermodynamic parameters implied the adsorption was spontaneous, endothermic. The adsorption performance of the new adsorbent toward uranium using fixed-bed column method was also investigated. The investigated adsorbent (Si-6G PAMAM-PPAAM) was successfully used to extract uranium from leach liquor of granitic rock sample.