An efficient and green synthesis is developed for the preparation of the arylidene isatinhydrazone derivatives 4a-m using a heterogeneous mesoporous acid catalyst of SBA-Pr-SO3H with a pore size of 6 nm under solvent free conditions. The hydrazones 4a-m were then analyzed by UV-Vis spectroscopy and the results were used for the calculation of the HOMO-LUMO band gap. In addition, the quantum chemical calculations were performed to provide an illustrative explanation for the obtained band gap; it is found that probably these molecules have a high tendency to donate electrons to the appropriate small-molecule acceptors with low energy and empty molecular orbital.
CITATION STYLE
Gholamzadeh, P., Mohammadi Ziarani, G., & Badiei, A. (2016). Application of SBA-Pr-SO3H in the green synthesis of isatinhydrazone derivatives: Characterization, UV-Vis investigation and computational studies. Journal of the Chilean Chemical Society, 61(2), 2935–2939. https://doi.org/10.4067/S0717-97072016000200017
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