Simultaneous Methylene Blue Adsorption and pH Neutralization of Contaminated Water by Rice Husk Ash

Abstract

In this study, the potential of rice husk ash (RHA) to act as an adsorbent for treating dye-containing wastewater was demonstrated. The RHA used in this study contained 91.7% silica, which was composed of crystalline (cristobalite and tridymite) and amorphous phases. The mechanochemical treatment of RHA led to an increase in its specific surface area from 6.2 to 14.6 m2/g in 15 min and dramatically improved its methylene blue (MB) adsorption ability. Langmuir adsorption isotherms revealed that the maximum adsorption capacity of the treated RHA was 8.59 mg/g, which is 2.45 times higher than that of raw RHA. pH-dependent adsorption studies on the RHA revealed that MB was adsorbed on the deprotonated Q3 silanol through electrostatic interactions. Moreover, the RHA adsorbent showed pH buffering at a pH value of approximately 7; thus, the pH of the solution could be neutralized simultaneously with the adsorptive removal of MB.