Low-Acid Leaching for Preferential Lithium Extraction and Preparation of Lithium Carbonate from Rare Earth Molten Salt Electrolytic Slag

Abstract

In this work, lithium was preferentially recovered through the low-acid leaching from rare earth molten salt electrolytic slag (REMSES) with a leaching temperature of 60 °C. The influence on lithium extraction was investigated in detail in different leaching conditions. The optimal conditions were as follows: liquid-to-solid ratio (10 mL/g), sulfuric acid concentration (0.8 mol/L), leaching time (60 min) and leaching temperature (60 °C). This yielded a lithium extraction rate of 98.52% and a lithium carbonate purity of 99.5%. It was fitted using an empirical model; the kinetics showed that internal diffusion control conformed to the low-acid leaching reaction, which had an apparent activation energy of 10.81 kJ/mol for lithium. The total profit from the whole process was USD 0.2576 when dealing with 1.0 kg of REMSES. Moreover, in the sulfuric acid system, the leaching reaction mechanism was carefully investigated between 30 and 90 °C. An innovative process of recovering lithium from REMSES was achieved with environmental friendliness and good economic returns. Compared to traditional leaching using concentrated sulfuric acid, this cleaner recycling method conforms to the concept of green, low-carbon sustainable development, with high lithium selectivity, low impurity content in the filtrate and low acid consumption.