Preparation of phthalocyanine immobilized bacterial cellulose nanocomposites for decoloration of dye wastewater: Key role of spacers

Abstract

We report the preparation of a series of spacer-incorporated, tetra-amino cobalt (II) phthalocyanine (CoPc)-immobilized bacterial cellulose (BC) functional nanocomposites (CoPc@s-BC). Four kinds of flexible spacers with different lengths-diethylenetriamine (DT), triethylenetetramine (TT), tetraethylenepentamine (TP) and pentaethylenehexamine (PH)-were covalently attached onto pre-oxidized BC for the synthesis of the spacer-attached BC, and the attached spacers' contents were carefully quantified. Using glutaraldehyde as a cross-linker, the CoPc catalyst was covalently immobilized onto the spacer-attached BC, and the immobilization steps were optimized by monitoring both the residual spacer contents and the resulting immobilized CoPc. All of the functionalization processes were characterized and confirmed by X-ray photoelectron spectroscopy (XPS). The series of spacer-incorporated, CoPc-immobilized BC nanocomposites, CoPc@s-BC, were used for the decoloration of dye wastewater. Both the adsorption capacity and adsorption rate were increased after the incorporation of spacers. When H2O2 was employed as an oxidant, dye molecules were catalytically oxidized with these nanocomposites. Electron paramagnetic resonance (EPR) spin-trapping results showed that the highly reactive hydroxyl radical (·OH) was involved in the catalytic oxidation process. The spacer length had a direct effect on the catalytic efficiency of CoPc@s-BC-the decoloration rate for CoPc@TP-BC was as high as 41 μmol·min-1·g-1, which was more than 50% higher than that without spacer.