Journal Article

Triple bonding to tin: Synthesis and characterization of the stannylyne complex trans-[Cl(PMe3)4W≡Sn-C6 H3-2,6-Mes2]

Angewandte Chemie - International Edition (2003) 42(4) 445-447
DOI: 10.1002/anie.200390135
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Abstract

Straightening out tin: The reaction of the dinitrogen complex 1 with the aryl tin(II) chloride 2 affords selectively the stannylyne complex 3. The molecular structure of 3 shows a very short W - Sn bond of 2.4902(8) Å and a linear coordinated tin atom (W-Sn-C=178.2(1)°). R=C6H3-2,4,6-Mes2, Mes=C6H2-2,4,6-Me3.

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Filippou, A. C., Portius, P., Philippopoulos, A. I., & Rohde, H. (2003). Triple bonding to tin: Synthesis and characterization of the stannylyne complex trans-[Cl(PMe3)4W≡Sn-C6 H3-2,6-Mes2]. Angewandte Chemie - International Edition, 42(4), 445–447. https://doi.org/10.1002/anie.200390135

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