A simple approach to room temperature phosphorescent allenylidene complexes

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Abstract

A warm (blue) glow: A stable bis-cyclometalated iridium(III) allenylidene complex is prepared from a bis-cyclometalated iridium(III) complex (see scheme). This strategy gives the first allenylidene complex that is phosphorescent at room temperature. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Kessler, F., Curchod, B. F. E., Tavernelli, I., Rothlisberger, U., Scopelliti, R., Di Censo, D., … Baranoff, E. (2012). A simple approach to room temperature phosphorescent allenylidene complexes. Angewandte Chemie - International Edition, 51(32), 8030–8033. https://doi.org/10.1002/anie.201203329

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