Iron-doped carbon aerogels: Novel porous substrates for direct growth of carbon nanotubes

Abstract

We present the synthesis and characterization of Fe-doped carbon aerogels (CAs) and demonstrate the ability to grow carbon nanotubes directly on monoliths of these materials to afford novel carbon aerogel-carbon nanotube composites. Preparation of the Fe-doped CAs begins with the sol-gel polymerization of the potassium salt of 2,4-dihydroxybenzoic acid with formaldehyde, affording K +-doped gels that can then be converted to Fe2+- or Fe3+-doped gels through an ion exchange process, dried with supercritical CO2, and subsequently carbonized under an inert atmosphere. Analysis of the Fe-doped CAs by TEM, XRD, and XPS revealed that the doped iron species are reduced during carbonization to form metallic iron and iron carbide nanoparticles. The sizes and chemical composition of the reduced Fe species were related to pyrolysis temperature as well as the type of iron salt used in the ion exchange process. Raman spectroscopy and XRD analysis further reveal that, despite the presence of the Fe species, the CA framework is not significantly graphitized during pyrolysis. The Fe-doped CAs were subsequently placed in a thermal C VD reactor and exposed to a mixture of CH4 (1000 sccm), H2 (500 sccm), and C2O4 (20 sccm) at temperatures ranging from 600 to 800°C for 10 min, resulting in direct growth of carbon nanotubes on the aerogel monoliths. Carbon nanotubes grown by this method appear to be multiwalled (∼25 nm in diameter and up to 4μm long) and grow through a tip-growth mechanism that pushes catalytic iron particles out of the aerogel framework. The highest yield of CNTs was grown on Fe-doped CAs pyrolyzed at 800°C treated at CVD temperatures of 700°C. © 2007 American Chemical Society.