Abstract: Pyridine-based Sb(III) bromide complexes with doubly charged cations, (PyC3)3[Sb2Br9]2 (I), (PyC4)[Sb2Br8] (II), (PyC5)2[α-Sb4Br16] (III), (PyC6)2[Sb2Br10] (IV), (4-MePyC2)2[Sb2Br10] (V), (4‑MePyC3)2[α-Sb4Br16] (VI), and (4-MePyC5)2[α-Sb4Br16] (VII), were synthesized and characterized by X-ray diffraction (CCDC nos. 2204718–2204724). The structures of these compounds were compared with the structures of related bromobismuthates(III).
CITATION STYLE
Usoltsev, A. N., Korol’kov, I. V., & Adonin, S. A. (2023). Bromoantimonates(III) vs. Bromobismuthates(III): Differences in the Tendency for the Formation of Polynuclear Complexes. Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 49(6), 345–349. https://doi.org/10.1134/S1070328423700598
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