Highly efficient electrocatalysts for seawater electrolysis under high current density: A critical review

Abstract

According to the International Energy Agency (IEA) strategy, water electrolysis will be a second priority for hydrogen production by 2030, which can support sustainable development goals (SDGs). However, for the large‐scale application, especially seawater electrolysis at a high current density, cost and durability of the electrocatalytic system need to be taken into account. Herein, fundamental mechanisms of seawater electrolysis in a wide range of pH values, potential electrocatalysts for overall water splitting, recent progress on synthesis electrocatalysts and basic principles for the evaluation of electrocatalysts are reviewed. Subsequently, critical parameters and issues for scaling‐up of seawater electrolyzers are critically discussed. Finally, future prospects for completing sustainable hydrogen production from seawater for sustainable development are outlooked. It is anticipated to offer guidelines for the design and production of innovative electrocatalysts with high electrocatalytic activity and durability for the industrial scale application.