Abstract
A one-pot synthesis of bulky bis-pocket A3B-type meso-cyano porphyrin, 5-cyano-10,15,20-tris(2,4,6-triphenylphenyl)porphyrin, has been accomplished via trifluoroacetic acid (TFA) catalyzed condensation of pyrrole and 2,4,6-triphenylbenzaldehyde in an acceptable yield of about 4%. DDQ served as oxidant and the cyanating agent.
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Liu, Z. Y., Mahmood, M. H. R., Wu, J. Z., Yang, S. B., & Liu, H. Y. (2017). Unexpected Synthesis of a Bulky Bis-Pocket A3B-Type Meso-Cyano Porphyrin. Molecules, 22(11). https://doi.org/10.3390/molecules22111941
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