Effect of thermal annealing on scintillation properties of Ce:Gd2Y1Ga2.7Al2.3O12 under different atmosphere

Abstract

Cerium-doped 1% Ce:Gd2Y1Ga2.7Al2.3O12(GYGAG) single crystal samples grown via Czochralski method were annealed under air, O2 and N2 atmospheres from 350 to 1400 °C. The X-ray excited luminescence spectra, energy spectra and UV as well as thermally stimulated luminescence (TSL) spectra were performed comparatively on “as-grown” and thermally annealed samples. It was found that the luminescence efficiency after annealing in air and O2 was significantly enhanced compared to the non-annealed samples and this phenomenon was suggested to be caused by the existence of some oxygen vacancies in the Ce:GYGAG crystals. And the oxygen vacancies in the as-grown GYGAG crystals can be effectively eliminated by means of annealing in O2 containing atmosphere without changing the luminescence mechanism. From the TSL curves before and after annealing, three traps within 77–650 K were found to be related to oxygen vacancies.