Darstellung und Kristallstrukturen von LiGaCl4 und LiGaI4/ Preparation and Crystal Structure of LiGaCL 4 and LiGaI 4

  • Hönle W
  • Hettich B
  • Simon A
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Abstract

The crystal structures of LiGaCl 4 and LiGaI 4 have been determined by single crystal X-ray methods. Both compounds are isotypic with LiAlCl 4 and characterized by LiX 6 octahedra and GaX 4 tetrahedra. Mean bond lengths are: d̄(Ga-X) = 217.4 pm (Cl) and 255.9 pm (I); d̄(Li-X) = 263.9 pm (Cl) and 305.3 pm (I), respectively. Common features of the isotypic compounds LiGaX 4 (X = Cl, Br. I) are discussed.

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Hönle, W., Hettich, B., & Simon, A. (1987). Darstellung und Kristallstrukturen von LiGaCl4 und LiGaI4/ Preparation and Crystal Structure of LiGaCL 4 and LiGaI 4. Zeitschrift Für Naturforschung B, 42(2), 248–250. https://doi.org/10.1515/znb-1987-0222

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