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Preformed -allyl iron complexes as potent, well-defined catalysts for the allylic substitution

Angewandte Chemie - International Edition (2009) 48(39) 7251-7255
DOI: 10.1002/anie.200901930
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Abstract

Reanimation: Catalytically inactive π-allyl iron complexes are "reanimated" upon addition of N-heterocyclic carbene ligands such as 1,3-dimesitylimidazolin-2-ylidene (SIMES). A comparison of stoichiometric and catalytic allylic alkylation reactions shows the π-allyl mechanism to be active in this catalytic system. © 2009 Wiley-VCH Verlag GmbH & Co. KCaA.

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Holzwarth, M., Dieskau, A., Tabassam, M., & Plietker, B. (2009). Preformed -allyl iron complexes as potent, well-defined catalysts for the allylic substitution. Angewandte Chemie - International Edition, 48(39), 7251–7255. https://doi.org/10.1002/anie.200901930

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