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Through-space (cofacial) π-delocalization among multiple aromatic centers: Toroidal conjugation in hexaphenylbenzene-like radical cations

Angewandte Chemie - International Edition (2005) 44(32) 5133-5136
DOI: 10.1002/anie.200501005
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Abstract

(Chemical Equation Presented) Pi and doughnuts: Highly effective through-space conjugation among cofacial (aromatic) redox centers is established in stable hexaanilinylbenzene radical cations (1.+; π conjugation shown by toroid). The radical cations show unusual intervalence absorption bands and are quantitatively analyzed by Mulliken-Hush formulation. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

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Sun, D., Rosokha, S. V., & Kochi, J. K. (2005). Through-space (cofacial) π-delocalization among multiple aromatic centers: Toroidal conjugation in hexaphenylbenzene-like radical cations. Angewandte Chemie - International Edition, 44(32), 5133–5136. https://doi.org/10.1002/anie.200501005

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