Abstract
The first asymmetric oxidation of ester and amide lithium enolates 5 to optically active a-hydroxy carbonyl compounds 6 is reported using new, easily prepared, stable (camphorylsulfonyl)oxaziridines (+)-(2R,8aS)-3 and (-)-(2S,8aR)-4. Either enantiomer of 6 can be readily obtained because the configuration of the oxaziridine three-membered ring determines the product stereochemistry. © 1986, American Chemical Society. All rights reserved.
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CITATION STYLE
Davis, F. A., Haque, M. S., Ulatowski, T. G., & Towson, J. C. (1986). Asymmetric Oxidation of Ester and Amide Enolates Using New (Camphorylsulfonyl)oxaziridines. Journal of Organic Chemistry, 51(12), 2402–2404. https://doi.org/10.1021/jo00362a053
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