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[3+2] Annulation of Donor-Acceptor Cyclopropanes with Vinyl Azides

Synlett (2017) 28(9) 1091-1095
DOI: 10.1055/s-0036-1588703
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Abstract

A Sc(OTf)3-catalyzed reaction of vinyl azides with donor-acceptor cyclopropanes affords highly functionalized azidocyclopentanes in a diastereoselective fashion. The resulting azidocyclopentanes could be transformed into various cyclic scaffolds.

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Kaga, A., Gandamana, D. A., Tamura, S., Demirelli, M., & Chiba, S. (2017). [3+2] Annulation of Donor-Acceptor Cyclopropanes with Vinyl Azides. Synlett, 28(9), 1091–1095. https://doi.org/10.1055/s-0036-1588703

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