The use of two-dimensional NMR spectroscopy to determine the rates of and activation parameters for the 3,2-hydride shift in the 2-norboryn cation

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Abstract

Quantitative two-dimensional exchange spectroscopy has been used to determine the rates of and activation parameters for the 3,2-hydride shift in the 2-norbornyl cation. The results compare favorably with the published values obtained by line shape analysis. © ARKAT USA, Inc..

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Smith, K., Pan, H., Hondrogiannis, G., Mamantov, A., & Pagni, R. M. (2009). The use of two-dimensional NMR spectroscopy to determine the rates of and activation parameters for the 3,2-hydride shift in the 2-norboryn cation. Arkivoc, 2009(5), 68–74. https://doi.org/10.3998/ark.5550190.0010.507

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